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A broadcast signal intrusion is the hijacking of broadcast signals of radio , television stations , cable television broadcast feeds or satellite signals without permission or license. Hijacking incidents have involved local TV and radio stations as well as cable and national networks. Although television, cable, and satellite broadcast signal intrusions tend to receive more media coverage, radio station intrusions are more frequent, as many simply rebroadcast a signal received from another radio station. All that is required is an FM transmitter that can overpower the same frequency as the station being its rebroadcast. Other methods that have been used in North America to intrude on legal broadcasts include breaking into the transmitter area and splicing audio directly into the feed. As a cable television operator connects itself in the signal path between individual stations and the system's subscribers, broadcasters have fallen victim to signal tampering on cable systems on multiple occasions. The intrusion did not entirely affect the video signal but replaced the program audio with a six-minute speech about the destiny of the human race and a disaster to affect "your world and the beings on other worlds around you". The IBA confirmed that it was the first time such a transmission had been made. In , the person behind the intrusion was identified as journalist and pirate radio DJ Bob Tomalski , after journalist Tommie Trelawny, as part of investigative podcast The Interruption , discovered an old comment thread in a private Facebook group for pirate radio enthusiasts, which identified Tomalski as the perpetrator. At a. The interruption occurred during a presentation of The Falcon and the Snowman. The intrusion lasted between 4 and 5 minutes and was seen by viewers along the East Coast. The man, who during the interruption also threatened to hijack the signals of Showtime and The Movie Channel , was later caught and identified as John R. MacDougall of Ocala, Florida.

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Because of the generally strong relation between age and A/I, amino-acid epimerization analysis of individual shells can be used to identify mixed-age deposits. Two hypotheses were investigated: the keto–enol tautomerism and the base-mediated racemization, through an enolate intermediate. The results. In addition, the α-carbonyl vinyl esters were stable; hence, they could be isolated, purified, characterized, and stored for a long time. Both. Using samples of modern bear teeth dentine heated at 65°C, 85°C (up to 53 days), and °C (up to 71 days), and three independently dated fossil bear teeth, we. Amino acid racemization has also been employed in dating Holocene effects of time and temperature on the amino acid racemization/epimerization process. Masters and Bada (, ) compared the extent of isoleucine epimerization in radiocarbon dated shells and found distinct divergences. Using one modern sample and four fossil samples (dating to yr B.P.) of Differences in the temperature dependence of racemization/epimerization.

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Brown Geoscience Research Institute. The possibilities for using these characteristics as a means for determining fossil age are frustrated by variations of the amino acid pattern among individual living organisms of the same species, and by the critical dependency Epimerization vs racemization dating the racemization probability for an amino acid molecule on temperature, water concentration in the environment, alkalinity of the environment, association with other molecules free state or a component Epimerization vs racemization dating a macromoleculesize of the macromolecule of which it may be a component, specific location in the structure of a macromolecule, catalytic effect of clay surfaces with which it may be associated, presence of aldehydes and metal ions, concentration of buffer compounds in the environment, and ionic strength of the environment. Due to the strong dependency of racemization rates on temperature, water concentration, and alkalinity, uncertainties regarding conditions of preservation can leave amino-acid-based age relationships among even similar fossils open to question. The survival of amino acids in fossils from the Paleozoic era and Epimerization vs racemization dating trend for the apparent racemization rate constant to decrease with conventional fossil age assignment raise a serious question concerning the accuracy with which radioisotope age data have been used Epimerization vs racemization dating represent the real-time history of fossils. The instability of the twenty amino acids which are the building blocks of proteins provides a possible means for determining the ages of fossils. A preliminary recognition of this possibility appeared in the scientific literature 30 years ago Abelson Since Epimerization vs racemization dating acids have widely varying degrees of stability, after the death of an organism the less stable amino acid components will decompose more rapidly than those which are more stable, producing an amino acid signature that is increasingly distributed toward the more stable components as time progresses Hare and AbelsonEpimerization vs racemization dating et al. Because of the range of variation among individual members of the same species Hare and AbelsonHare and MittererKing and HareJopeamino acids may be expected to provide at best only a broad indication of fossil age. Uncertainty as to the extent to which modern organisms represent in detail the characteristics of their ancient counterparts introduces additional lack of precision in a fossil age based on amino acid ratios. Amino acids have been reported from fossils distributed throughout the geologic column Florkin Since detectable levels of many amino acids are expected to survive only a few million years, at best, these observations are an enigma Abelson Therefore it has been suggested that the amino acids found in older fossils, such as those from Cambrian sediments, e. Investigation of this suggestion has identified residual amino acids in Silurian graptolites million year putative age Florkin

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